On the Abundance of Holmium in the Sun

The abundance of holmium (Z = 67) in the Sun remains uncertain. The photospheric abundance, based on lines of Ho II, has been reported as +0.26 +/- 0.16 (on the usual scale where log(H) = 12.00), while the meteoretic value is +0.51 +/- 0.02. Cowan code calculations have been undertaken to improve the partition function for this ion by including important contributions from unobserved levels arising from the (4f^{11}6p + 4f^{10}(5d + 6s)^{2}) group. Based on 6994 computed energy levels, the partition function for Ho II is 67.41 for a temperature of 6000 K. This is approximately 1.5 times larger than the value derived from the 49 published levels. The new partition function alone leads to an increase in the solar abundance of Ho to log(Ho) = +0.43. This is within 0.08 dex of the meteoretic abundance. Support for this result has been obtained through LTE spectrum synthesis calculations of a previously unidentified weak line at 3416.38 A in the solar spectrum. Attributing the feature to Ho II, the observations may be fitted with log(Ho) = +0.53. This calculation assumes log(gf) = 0.25 and is uncertain by at least 0.1 dex.Comment: 16 pages, 4 figures, accepted for publication in Solar Physic

Implementing TOPbase/Iron Project: Continuous Absorption from Fe II

We discuss implementation of TOPbase and Iron Project opacities for stellar spectral codes. We use a technique employed by Peach, where a Boltzmann-averaged cross section is calculated for selected temperatures, and the opacity obtained from double interpolation in temperature and wavelength. It is straightforward to include {\it all} levels for which cross sections have been calculated. Boltzmann-averaged cross sections for Fe II show a local maximum between 1700 and 2000[A]. We suggest this feature arises from 3d^5 4snl to 3d^5 4pnl transitions within Fe II. IUE spectra of iron-rich CP stars show local minima in this region. Theoretical calculations of a representative stellar continuum demonstrate that Fe II photoionization contributes significantly to the observed minima.Comment: 6 pages, 5 figures. See http://www.astro.lsa.umich.edu/users/cowley/paper2r for better definition figure

New Mn II energy levels from STIS-HST spectrum of the HgMn star HD 175640

The NIST database lists several Mn II lines that were observed in the laboratory but not classified. They cannot be used in spectrum synthesis because their atomic line data are unknown. These lines are concentrated in the 2380-2700 A interval. We aimed to assign energy levels and log gf values to these lines. Semi-empirical line data for Mn II computed by Kurucz were used to synthesize the ultraviolet spectrum of the slow-rotating, HgMn star HD 175640. The spectrum was compared with the high-resolution spectrum observed with the HST-STIS equipment. A UVES spectrum covering the 3050-10000 A region was also examined. We determined a total of 73 new energy levels, 58 from the STIS spectrum of HD 175640 and another 15 from the UVES spectrum. The new energy levels give rise to numerous new computed lines. We have identified more than 50% of the unclassified lines listed in the NIST database and have changed the assignement of another 24 lines. An abundance analysis of the star HD 175640, based on the comparison of observed and computed ultraviolet spectra in the 1250-3040 A interval, is the by-product of this study on Mn II.Comment: Paper accepted by Astronomy & Astrophysic

The Puzzling Spectrum of HD 94509

The spectral features of HD 94509 are highly unusual, adding an extreme to the zoo of Be and shell stars. The shell dominates the spectrum, showing lines typical for spectral types mid-A to early-F, while the presence of a late/mid B-type central star is indicated by photospheric hydrogen line wings and helium lines. Numerous metallic absorption lines have broad wings but taper to narrow cores. They cannot be fit by Voigt profiles. We aim to describe and illustrate unusual spectral features of this star, and make rough calculations to estimate physical conditions and abundances in the shell. Furthermore, the central star is characterized. We assume mean conditions for the shell. An electron density estimate is made from the Inglis-Teller formula. Excitation temperatures and column densities for Fe I and Fe II are derived from curves of growth. The neutral H column density is estimated from high Paschen members. The column densities are compared with calculations made with the photoionization code Cloudy. Atmospheric parameters of the central star are constrained employing non-LTE spectrum synthesis. Overall chemical abundances are close to solar. Column densities of the dominant ions of several elements, as well as excitation temperatures and the mean electron density are well accounted for by a simple model. Several features, including the degree of ionization, are less well described. HD 94509 is a Be star with a stable shell, close to the terminal-age main sequence. The dynamical state of the shell and the unusually shaped, but symmetric line profiles, require a separate study.Comment: 10 pages, 9 tables, 13 figures; accepted for publication by Astronomy and Astrophysic

Line identification studies using traditional techniques and wavelength coincidence statistics

Traditional line identification techniques result in the assignment of individual lines to an atomic or ionic species. These methods may be supplemented by wavelength coincidence statistics (WCS). The strength and weakness of these methods are discussed using spectra of a number of normal and peculiar B and A stars that have been studied independently by both methods. The present results support the overall findings of some earlier studies. WCS would be most useful in a first survey, before traditional methods have been applied. WCS can quickly make a global search for all species and in this way may enable identifications of an unexpected spectrum that could easily be omitted entirely from a traditional study. This is illustrated by O I. WCS is a subject to well known weakness of any statistical technique, for example, a predictable number of spurious results are to be expected. The danger of small number statistics are illustrated. WCS is at its best relative to traditional methods in finding a line-rich atomic species that is only weakly present in a complicated stellar spectrum